General procedure for the synthesis of amides from azo compounds by smticl 4. Azo compounds are compounds bearing the functional group diazenyl r. A detailed theoretical uv study of some azo acrylate compounds. Synthesis of some azo compounds and a study of their properties.
The two compounds, which can be viewed as being composed. Synthesis of most azo compounds involves diazotization of a primary aromatic amine. Variation in molecular stacking resulting from the different polarity of liquid crystalline molecules. Azo dyes represent vital components to the fabrics and textiles industries, and diazonium salts are the building blocks that these compounds are made from. Epr spin trapping study of the decomposition of azo compounds in aqueous solutions by ultrasound. Aldamineheterocyclic ligands have been prepared through condensation step to formation aldamine compound as a starting compound for production all ligands in this study, which is used in. Potential for use as sonodynamic sensitizers for cell killing. Compounds containing one or more azo groups nn linked to two carbon atoms have a variety of uses. The study indicated that the type of lateral groups and their position adversely affects the mesomorphic properties of these compounds. Synthesis, azo compounds, guanine and, biological activity, bacteria introduction azo ligands of heterocyclic. Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated gently, then water 10 ml was added in order to dissolve the solid. Azobenzene is the prototypical aromatic azo compound. Studies on synthesis and spectral characterization of some. Gaskelld, xiulin fana, ji chena, tao denga, ruixing.
The most important contribution of azo compounds to radical chemistry is in their role as reaction initiators. The mixture was cooled to 0 c in an ice bath with stirring. Density functional study cavus ms 1, gur m 2, vurdu cd 1, kocaokutgen h 4, sayiner g 3 and kandemirli f 1. Hence, a series of naphtholic azo dyes 19 were synthesized via diazotization of substituted aniline.
A detailed theoretical uv study of some azoacrylate. Reduction azides are reduced to tinsubstituted amines by. Irradiation at 254 nm photochemically cleaves the ring and the resulting azo compounds often absorb little at these wavelengths and the. Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated. Synthesis, characterization of new azo compounds and their. Epr spin trapping study of the decomposition of azo. It exists mainly as the trans isomer, but upon illumination. In general azo resorcinol compounds can exist in azo hydrazone tautomeric forms. Synthesis, spectroscopic, thermodynamics and kinetics.
Combinatorial synthesis of azo dyes linfield college. Azo compounds as a family of organic electrode materials. But in our study, all the spectral data show that 2substituted phenyl azo 4,6. Pdf on aug 1, 2011, omer rasheed published new directions in the chemistry of azocompounds find, read and cite all the research you.
Biodegradation of azo dye compounds premier publishers. Photochemical and electronic properties of conjugated bis. The environmental, health and economic impacts of textile. Aryl azo compounds are usually stable, crystalline species. Study on the reactions of azo compounds with acyl halides. Azo dyes are extremely important in variety of industries for variety of technical purposes. Mostly, synthesis of azo compounds involves diazotization of substituted primary. They are compound bearing the functional group rnnr in which r and r can be either alkyl or aryl groups. The azo components used were 8hydroxyquinoline, resorcinol, pyrogallol, and 7iodo8hydroxy5quinolinesulfonic acid, while the diazol components were sulfanilamide and a number of its derivatives. Synthesis and identification symmetrically azo dyes.
Biodegradation of azo dye compounds kamlesh shah department of biotechnology, p. Our interest in this molecule stems from its ability to act as a diamine. Applying different extraction procedures and different analytical technologies toxicological assessment. Gromova, practical manual of spectrophotometry and. They are a commercially important family of azo compounds, i. Preparation of azo compounds for the study of inhibition. New azo mesogenic compounds with oh, ch 3, cl, and f side groups on the central benzene nucleus were synthesized. A green dehydrogenation of hydrazo compounds using basic alumina or kfalumina under solventfree conditions afforded azo compounds in good to excellent yields. On the chargetransfer excitations in azobenzene maleimide. The study indicated that the type of lateral groups and their position adversely. Developing a method for the analysis of azo dyes using the.
Reduction azides are reduced to tinsubstituted amines by reaction with tin hydrides. Photoswitchable systems with chargetransfer ct transitions have gained much attention during the recent years because of their many emerging applications. Azo compounds as a family of organic electrode materials for alkaliion batteries chao luoa, oleg borodinb, xiao jia,c, singyuk houa, karen j. Study the electrical conductivity for a new azo compound.
Synthesis of azo compounds organic chemistry portal. A study of the inhibition of tumor growth in mice and rats with azo compounds. Novel compounds 222hydroxy4nitrophenyl hydrazono1,3diphenyl propane1,3dione and 222hydroxy4nitrophenyl hydrazono1phenyl butane1,3dione are prepared on the. Variation in molecular stacking resulting from the. Synthesis and characterization of azo compounds and study of the. Compounds 183 are convenient photochemical azo precursors. Classifications, properties, recent synthesis and applications of azo. Further work on transformation of the cobaltii complex of 2. As well as the study was achieved through the complexes formed between these a new prepared symmetrically azo dyes. Journal of chemical and pharmaceutical research, 2016, 85. Biological studies of syntheised azo compounds of indole.
Azo compound, any organic chemical compound in which the azo group. However, such compounds are seldom used as polymerization initiators and further discussion on this subject is beyond the scope of this chapter. A number of studies have shown that, in aqueous media, many azodyes, and. Azo dyes are class of compounds containing a nn double bond generally connected to aromatic ring, due to their ability to absorb visible light and ease of. Azo group is stabilised by becoming part of extended delocalised. Synthesis and characterization of azo compounds and study. Most common method variables are column chemistry stationary phase. New directions in the chemistry of azocompounds research. Azo compounds are very important molecules and have attracted much attention in both academic and applied research 1520. The azo components used were 8hydroxyquinoline, resorcinol, pyrogallol, and 7iodo8hydroxy5. Azo dyes represent the largest production volume of dye chemistry. Asian journal of research in chemistry and pharmaceutical. Study of removal techniques for azo dyes by biosorption. When the reactivity of the aryl group is increased by the presence of electron donor substituents or fused rings, the direct cn bond formation leads to.
Synthesis of some azo compounds and a study of their. Where r and r are arene groups more stable than alkyl groups. Likewise, several case studies have linked azo pigments with basal cell carcinoma. The unit containing the nitrogennitrogen double bond is called an azo group.
The antibacterial activities of the compounds were studied using gram positive and gram negative microorganism. Antioxidant activity study hala s alatbi, bushra k alsalami and iqbal j alassadi university of basrah,college of science, department of chemistry,basrahiraq. Under nitrogen atmosphere, 1 mmol of azo compound 1 dissolved in dry thf 1 ml was added to the solution. In the following, we have summarized some recent syntheses of azo dyes and. Pdf new directions in the chemistry of azocompounds.
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